Date of this Version
1-23-2017
Document Type
Article
Abstract
The hexanuclear title compound, [{Cu3(3-OCH3)(-C3H2ClN2)3}2(-C3H2ClN2)3(6-Cl)] or [Cu6(C3H2ClN2)9(CH3O)2Cl], crystallizes in the space group Pbcn, with individual molecules being located on a twofold rotation axis. The molecule adopts a trigonal prismatic shape, with two trinuclear units linked by three 4-chloropyrazolate ligand bridges by encapsulating a Cl- anion in a 6-coordination mode. In the crystal, individual molecules are stacked into rods parallel to [1-10] that are arranged in a pseudo-hexagonal packing. Cohesion between molecules is accomplished through weak C-HCl interactions.
Recommended Citation
Shi, K., Mathivathanan, L. & Raptis, R. G. (2017). Acta Cryst. E73, 266-269.
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Comments
Originally published in Acta Crystallographica Section E.
Acta Crystallographica Section E adheres to the Budapest Open Access Initiative definition of open access. Users have the right to read, download, copy, distribute, print, search, or link to the full texts of these articles.