Reduction of Pertechnetate from Off-gas Condensate using Aged Zero-valent Iron as a Reducing Agent
Master of Science (MS)
First Advisor's Name
Dr. Shonali Laha
First Advisor's Committee Title
Second Advisor's Name
Dr. Berrin Tansel
Second Advisor's Committee Title
Third Advisor's Name
Dr. Walter Tang
Third Advisor's Committee Title
Fourth Advisor's Name
Dr. Yelena Katsenovich
Fourth Advisor's Committee Title
Fifth Advisor's Name
Dr. Hilary Emerson
Fifth Advisor's Committee Title
Date of Defense
The Hanford site located in Washington State was one of the major nuclear processing facilities in the U.S. where plutonium was produced between the 1940s and the 1980’s. As a result of this forty yearlong production, approximately 53 million gallons of radioactive waste was generated and currently stored in 177 single and double shelled underground tanks. There were around 60 major and minor leaking incidents in the tanks through the years. These leaking incidents were wakeup calls to a search for an effective long term disposal solution. This paper will concentrate on the low activity waste (LAW), specifically the radioactive element technetium (Tc). Tc-99 is radioactive with a half-life of 211,000 years, formed during nuclear fission of Uranium-235. Tc-99 can be found in different oxidation states. However, Tc(VII), as pertechnetate anion (TcO 4 - ), is the most abundant in Hanford low activity aqueous waste due to its high solubility.
Currently there is no operational treatment plant at the site, but, once the treatment plant starts operation, the planned technique for the LAW is vitrification. Because of the higher volatility of technetium, this method can be challenging to accomplish. Here, we investigate another way of dealing with this highly volatile Tc(VII) via zero valent iron (ZVI). This material could be used to reduce Tc(VII) into a less volatile isotope Tc(IV) followed by possible precipitation.
Gebru, Abraham T., "Reduction of Pertechnetate from Off-gas Condensate using Aged Zero-valent Iron as a Reducing Agent" (2019). FIU Electronic Theses and Dissertations. 4223.
In Copyright. URI: http://rightsstatements.org/vocab/InC/1.0/
This Item is protected by copyright and/or related rights. You are free to use this Item in any way that is permitted by the copyright and related rights legislation that applies to your use. For other uses you need to obtain permission from the rights-holder(s).